Adele's theme for the new Bond film Skyfall has shot to the top of the iTunes chart within hours of its release.
The track is hotly tipped to become the first 007 theme to make it to number one in the official chart when it is announced on Sunday.
Previous Bond theme artists have all failed to take their songs to the top of the charts, including Sir Paul McCartney, Sir Tom Jones and Madonna, while Duran Duran made it to just number two in 1985 with A View to a Kill.
