Their chemistry in 2005's Mr and Mrs Smith was sizzling enough to drive huge crowds to the box office, and - of course - to build a long-term relationship.
And a friend of Brad Pitt's has sensationally revealed in a new authorised interview with Esquire that Brad has placed a self-imposed ban on filming sex scenes with other women out of respect for Angelina Jolie.
So that means his steamy scenes all now take place at home, which makes his eldest daughter Zahara, eight, cringe... he revealed to the magazine.
